試卷名稱:113年 - 113 台灣聯合大學系統_碩士班招生考試_化學類:物理化學#122381
年份:113年
科目:研究所、轉學考(插大)◆物理化學
3. Which valence bond wavefunction for He is not a proper wavefunction because it violates the Pauli exclusion principle? (Please note: the numbers 1 and 2 represent the two electrons of He, N is the normalization constant, 1sA and 1Se represent the atomic orbitals, and a and B are spin wavefunctions.)
(A) φ(1,2) = N[1sA(1)1sB;(2)-1SA(2)1sB(1)][a(1)B(2)-a(2)B(1)]
(B)φ(1,2)=N[1sA(1)1sB(2)+1sA(2)1sB(1)][a(1)B(2)-a(2)B(1)]
(C) φ(1,2)=N[1sA(1)1sB(2)-1sA(2)1SB(1)][(1)β(2)+a(2)β(1)]
(D)φ(1,2)=N[1sA(1)1sB(2)-1sA(2)1SB(1)][a(1)a(2)]
(E)φ(1,2)=N[1sA(1)1sB(2)-1SA(2)1SB(1)][β(1)β(2)]