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1. Which of the following combinations of quantum numbers are not allowed?
I. n= 3, l= 3, ml= 0, ms= -1/2
II. n= 4, l= 3, ml= 2, ms= -1/2
III. n= 4, l= 1, ml= -1, ms= +1/2
IV. n= 5, l= -4, ml= 2, ms= +1/2
(A) III, IV
(B) II, III
(C) I, II
(D) I, IV
(E) I, III, IV

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