88. Choose the correct statement.
(A) A reaction that exhibits a negative value of △S cannot be spontaneous.
(B) Exothermic reactions are always spontaneous.
(C) Free energy is independent of temperature,
(D) At constant pressure and temperature, a decrease in free energy ensures an increase in the entropy of the system.
(E) None of the above.
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統計: A(1), B(0), C(0), D(10), E(6) #3222855
統計: A(1), B(0), C(0), D(10), E(6) #3222855
詳解 (共 1 筆)
#6341302
(A) 負△S值的反應不能自發
錯,自發反應的判斷不僅僅取決於△S,還要考慮△H和溫度
(B) 放熱反應總是自發的
錯,放熱反應(△H<0)有助於反應自發,但如果△S是負的,且溫度很低,反應可能不自發
(C) 自由能與溫度無關
錯,△G和溫度有關,ΔG=ΔH−TΔS
(D) 定壓和定溫下,減少自由能確保系統的熵增加
錯,雖然△G < 0是自發條件,但不代表系統熵一定增加;自由能減少可能來自於焓減少(放熱反應)或熵增加,兩者都可能導致自由能減少
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