110年 - 110 國立中山大學碩士暨碩士專班招生考試_化學系碩士班:物理化學及分析化學#106071

選擇題 (30)

1.For an ideal gas in a perfect Carnot engine, which of the following processes can be used to do the greatest work? (A) Reversible adiabatic expansion (B) Reversible isothermal compression (C) Reversible adiabatic compression (D) Reversible isothermal expansion

2. In an adiabatic free expansion process for an ideal gas, which term is NOT zero? (A)△U (internal energy change) (B)W (Work) (C) △T (temperature change) (D)

3.In Joule-Thomson experiment, which thermodynamic term is zero? (A) △H (Enthalpy change) (B)△U (internal energy change) (C) △V (Volume change) (D) △P (Pressure change)

4.What is the correct relationship between C_v and S?(A) (B) as dv=o, ds =dT(C) as dp-=o, ds =dT (D)as dv=0, ds =dP

5.If we mix 0.4 mole of pure benzene with 0.6 mole of pure toluene at temperature T. Assume this mixture is an ideal solution. What is△S? (A)0.4RIn0.4 +0.6Rn0.6 (B) 0.4RTIn0.4 + 0.6RTIn0.6 (C) 0.4RIn0.6+0.6RIn0.4 (D) 0.4RTIn0.6+ 0.6RT1n0.4

6.What is the activity of 1 mole liquid water at 832.45 bar, 300 K? (A) 1.074 (B) 403.4 (C)1.822 (D)1.0007

7.How many wavenumbers () are equivalent to the energy at 300 Kelvin? (A) 100 (B) 53 (C) 0.371 (D) 208

8.What is the boundary conditions for a "'particle in a box" model? (A)(0)=(L)=0(B)(0)=(L)=∞(C)(0)=(L)=1(D)(0)=0,(L)=∞

9. If a potential function of a diatomic molecule can be described by a Morse potential, V(x) =, what is the force constant k? (A)βDe(B) 1/2βDe (C) 1/2 β²De² (D) 2 β²De²

10. The is an eigenfunction of, so what is the eigenvalue? (A) (B) (C) (D)1

11. What is the ground state term of molecular oxygen? (A)³P (B)(C)(D)

12. To measure a correct rate coefficient, which order reaction does not require to know the absolute concentrations of reactants? (A) order (B) order (C) order (D) order

13. If the population decay channels of the excited state decay include three channels, such as fluorescence channel (k_F), internal conversion channel (), and intersystem crossing channel (), what is the observed fluorescence lifetime Tr? (A)1/ k_F (B) 1/ (k_F+ ) (C) 1/ (k_F+ + ) (D) 1/ (k_F+ )

14. The rate constant for the reaction of at 575 K and 716 K. Estimate the value of Ea from these data. (Assuming the Ea and pre- exponential factor are temperature independent) (A)185 (B) 158 (C) 116 (D) 161

15. In statistical thermodynamics, which kind of molecular motion has greatest contribution to the entropy? (A) Rotation (B) Vibration (C)Translation (D)electronic transition

16. If we compare two means from two samples, which test do we use? (A) t-test (B) F-test (C) Q-test (D) R-test

17. Which of the following statements are INCORRECT? (A) 100 ppb (B) The number 1.2500 x 10⁴has five significant figures. (C)0.02(±0.02)+0.01(±0.02)-0.02(±0.03)=0.01(±0.04) (D) Molality is the number of moles of a substance per liter of solution.

18. Which of the following statements concerning the detection of Random error are INCORRECT? (A) Random error is also called an indeterminate error. (B) Random error has a Gaussian normal distribution. (C) Random error is always present in a measurement. (D) Random error can be reduced by decreasing the number of measurements

19. The calibration curve equation for quantifying standard was I = 51.00 x [ ] + 1.00, where I is the intensity and the concentration is in micromole/L. The reagent blank, measured by three repeated experiments, gave a value of 0.30± 0.04. What is the detection limit for Cu2t based on a signal-to-noise ratio of 2? (A) 1.56 nM. (B) 1.35 nM. (C) 2.56 nM. (D) 2.35 nM.

複選題

20. Which of the following statements concerning titration are INCORRECT? (A) The pH at the midpoint, the point halfway on the titration curve to the equivalence point, is equal to the pK_a of the weak acid. (B) The pK_a values of a diprotic acid H₂A are= 8.00. At pH 9.00, the major species are(C) The equivalent volume for titrating 50.00 mL of a solution (0.05 M in iodide ions and 0.08 M in chloride ions) with 0.1 M silver nitrate is 60 mL. (D) In EDTA titration, ammonia often is required to prevent the precipitation of metal ions.

複選題
21. Which of the following statements concerning voltammetry are INCORRECT? (A) The working electrode carries out the electrochemical even of interest. (B) The progressive scanning of carbon electrodes is extended to more negative potentials than platinum or gold electrodes. (C) A sharp peak profile for each species is observed in differential pulse voltammetry (D) A charging current results from redox reactions at the working electrode and the auxiliary electrodes.

複選題
22. Which of the following statements concerning capillary electrophoresis are INCORRECT? (A) Micellar electrokinetic chromatography is based on the addition to the buffer solution of a micellar "pseudo-stationary" phase. (B) Capillary zone electrophoresis allows uncharged analytes to be separated. (C) The intrinsically low flow-rate of capillary electrophoresis is advantageous to connect with electrospray ionization-mass spectrometry. (D) The electroosmotic flow remains almost constant with an increase in electric field strength.

23. Which of the following statements concerning surface spectroscopic methods are INCORRECT? (A) X-ray photoelectron spectroscopy is useful to identify the elemental composition of the sample and determine its valance state. (B) The elemental hydrogen in the sample can be detected by X-Ray photoelectron spectroscopy. (C) The process of Auger electron spectroscopy (AES) includes atomic ionization, electron emission, and analysis of the emitted Auger electrons (D) In X-Ray photoelectron spectroscopy, detection limits for most of the elements are in the parts per thousand range.

24. Which of the following statements concerning inductively coupled plasma-optical emission spectrometry (ICP-OES) and inductively coupled plasma-mass-spectrometry (ICP-MS) are INCORRECT? (A) ICP-OES can be used to analyze isotopes of elements (B) ICP-MS is more sensitive than ICP-OES (C) The steps associated with ICP-MS analysis of the samples include introduction-atomizing, ionization, mass separation, and detection (D) ICP-OES and ICP-MS both provide high throughput multi-element analysis.

25. The activity coefficients of H⁺ and OH^- are 0.83 and 0.76 when the ionic strength is 0.1. The pH of water containing 0.10 M LiNO₃ at 25℃ are (A) 6.98 (B) 7.00. (C) 7.02 (D) 7.04

26. Which of the following statements concerning gas chromatography (GC) are INCORRE CT? (A) The split injection is selected when the concentration of the target analyte in the sample is at trace level. (B) GC combined with a flame-ionization detector is used extensively for the detection of hydrocarbons. (C) GC in conjugation with a thermal-conductivity detector is useful for the analysis of a mixture of gases (D) A polydimethylsiloxane-based polymer is heavily used as a stationary phase in GC.

27. Which of the following methods concerning high-performance liquid chromatography (HPLC) are INCORRECT? (A) Ion-pair chromatography is powerful for the separation of metal ions due to the addition of ion- pair reagents. (B) Size-exclusion chromatography is useful for the separation of large-sized macromolecules, but it suffers from limited resolution and long analysis time (C) In reversed-phase HPLC, polar analytes elute carlier than nonpolar ones. (D) In ion-exchange chromatography, ion exchangers bind preferably ions of higher charge and increased hydrated radius

28. Which of the following methods concerning absorption are INCORRECT? (A) UV-Visible spectroscopy of organic compounds is usually associated with n → π*and π → π*(B) The intensity of absorbance is proportional to the log of the absorbing species concentration (C) An atomic absorption spectrum consists of a series of line peaks (D) X-ray absorption spectroscopy (XAS) can probe the chemical surroundings around an atom of interest.

29. Which of the following statements concerning fluorescence are INCORRECT? (A) The lifetime of fluorescence is s. (B) The difference between the excitation and emission wavelengths is called the Stokes Shift. (C) Fluorescence intensity is sensitive to environmental factors, such as pH and solvent polarity. (D) The fluorescent quantum yield is dependent of excitation intensity.