35. Which carbons are released first as $\mathrm{CO}_{2}$ in the metabolism of glucose to $\mathrm{CO}_{2}$?
(A) carbons 1 and 2
(B) carbons 3 and 4
(C) carbons 5 and 6
(D) carbons 1 and 6
(E) none of the above.

35. Which carbons are released frst as CO2 in the metabolism of glucose to CO2? (A) carbons 1 and 2 (B) earbons 3 and 4 (C) carbons 5 and 6 (D) carbons 1 and 6 (E) none of the above.

35. Which carbons are released first as CO2 in the metabolism of glucose to CO2? (A) carbons 1 and 2 (B) carbons 3 and 4 (C) carbons 5 and 6 (D) carbons 1 and 6 (E) none of the above.

36. Which of the following scientists demonstrated that DNA, rather than proteins, is the genetic material? (A) F. Sanger (B) J. D. Watson and H. C. Crick (C) A. D. Hershey and M. Chase (D) S. Altman and T. Cech (E) S. B. Prusiner.

37. All of the following are paired with their preferred substrate except: (A) brain: fatty acids (B) heart: fatty acids (C) anaerobic skeletal muscle: glucose (D) red blood cell: glucose (E) adipose tissue: fatty acids.

38. ______ is considered an adapter molecule that links an amino acid to its codon(s). (A) mRNA (B) rRNA (C) tRNA (D) ssRNA (E) miRNA.

39. ______ within the ribosome is responsible for polypeptide synthesis. (A) aminoacyl-tRNA synthetase (B) met-aminopeptidase (C) degradase (D) ubiquitin (E) peptidyl transferase.

40. Which tautomeric form of ribose predominates in solution? (A) $\alpha$-pyranose (B) $\beta$-pyranose (C) $\alpha$-furanose (D) $\beta$-furanose (E) all of the above.

1. Which of the following is NOT correct description about the Maxwell relation in thermodynamics? (A) $\left(\frac{\partial T}{\partial V}\right)_S = -\left(\frac{\partial P}{\partial S}\right)_V$ (B) $\left(\frac{\partial T}{\partial P}\right)_S = \left(\frac{\partial V}{\partial S}\right)_P$ (C) $-\left(\frac{\partial S}{\partial V}\right)_T = \left(\frac{\partial P}{\partial T}\right)_V$ (D) $-\left(\frac{\partial S}{\partial P}\right)_T = \left(\frac{\partial V}{\partial T}\right)_P$

2. At $298.15 \mathrm{~K}$, the reaction $\mathrm{SOCl}_{3(1)} + \mathrm{H}_{2} \mathrm{O}_{(1)} \rightarrow \mathrm{SO}_{2(g)} + 2 \mathrm{HCl}_{(g)}$ is endothermic and the equilibrium lies well on the right-hand side. Which of the following statement is correct? (A) $\Delta S_{\mathrm{rxn}} < 0$ at $298.15 \mathrm{~K}$ (B) $\Delta G_{\mathrm{rxn}} > 0$ at $298.15 \mathrm{~K}$ (C) $\Delta H_{\mathrm{rxn}} < 0$ at $298.15 \mathrm{~K}$ (D) $\Delta G_{\mathrm{rxn}}$ becomes more negative when the temperature is raised.

3. The reaction $\mathrm{A} \rightarrow 2\mathrm{B}$ is spontaneous when (A) $\mu_{\mathrm{A}} > 2\mu_{\mathrm{B}}$ (B) $\mu_{\mathrm{A}} = 2\mu_{\mathrm{B}}$ (C) $\mu_{\mathrm{A}} > \mu_{\mathrm{B}}$ (D) $\mu_{\mathrm{A}} < \mu_{\mathrm{B}}$ ($\mu$ is the chemical potential)

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