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1(A).
X


66. The color difference between [CoCl4]2− and [Co(H2O)6]2+ can be supported by which concept?
(A) Redox process
(B) Spectrochemical series
(C) Disproportionation reaction
(D) van’t Hoff factor
(E) Hard-Soft Acid-Base


2(A).
X


68. For a reaction involving changes of reactant concentrations ([A]), what is the reaction order (m) when the correlation of ln [A] versus time (t) is a straight line?
(A) m=0
(B) m=1/2
(C) m=1
(D) m=2
(E) None of these


3(A).
X


74. Which is the major specie for a carbonate-containing solution at pH 8.5? (Ka1 = 4.3 × 10–7 , Ka2 = 4.8 × 10–11 for carbonic acid)
(A) CO2
(B) H2CO3
(C) HCO3
(D) CO32−
(E) C2O42−


4(A).
X


82. For corrosion of iron, which of the following statements is (are) true?
 I. Anode reaction: Fe → Fe2+ + 2e 
II. Cathode reaction: O2 + 2H2O + 4e → 4OH 
III. Moisture serving as a salt bridge 

(A) I
(B) III
(C) I and II
(D) I, II, and III
(E) None of the statement is true


5(A).
X


1. Consider the block and spring system shown in the drawing. On the earth’s surface the natural frequency is ω. The system is then transported into moon’s surface (Gravitational acceleration: gMoon = gEarth/6). How will the natural frequency of the system change? 5eeaddc7b6ca0.jpg
(A) 6ω
(B) 5eeadddd63b6d.jpgω
(C) ω/6
(D) ω/ 5eeadde7aae60.jpg
(E) The frequency doesn’t change.



6(A).
X


18. Which of the following options best describes the relationship between the following two compounds?
61108b4142050.jpg
(A) Constitutional isomers
(B) Stereoisomers
(C) Identical
(D) Not isomers, different compounds entirely.
(E) Conformers



7(A).
X


22. What are the hybridization state and geometry of the nitrogen atom in the following chemical structure?
   61108ba2bb575.jpg
(A) sp hybridized and linear geometry
(B) sp2 hybridized and trigonal pyramidal
(C) sp3 hybridized and trigonal pyramidal
(D) sp3 hybridized and trigonal planar
(E) sp3 hybridized and bent



8(A).
X


66. The lattice energy of NaI(s) is -686 kJ/mol, and its heat of solution is -7.6 kJ/mol. Calculate the hydration of energy of NaI(s) in kJ/mol.
(A) -678
(B) -694
(C) +678
(D) +694
(E) +15.2


9(A).

67. According to molecular orbital, which of the following molecules is diamagnetic?
(A) HF
(B) O2
(C) NO
(D) 6110934c9cf8f.jpg
(E) 6110936c3d388.jpg



10(A).
X


75. What is the appropriate representation of the repeating unit of the following polymer? 61109602b8244.jpg 6110962920265.jpg
(A) I
(B) II
(C) III
(D) IV
(E) V



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