27. MgO 與 NaCl 具有相同的面心立方晶體結構。每個離子最近鄰周圍有多少氧離子?
(A) 4
(B) 6
(C) 8
(D) 10
(E) 12

26. There are three types of cubic unit cells, including simple cubic (SC), face-centered cubic (FCC), and body-centered cubic (BCC). Which of the following statements is correct? (A) BCC has 4 atoms per unit cell. (B) FCC has the largest unit cell. (C) The coordination number of SC is 8. (D) FCC is alternatively called hexagonal close-packed structure. (E) In BCC, the atomic packing factor is 0.68.

28. Which of the following binary compounds has two different solid-state structures? (A) NaCl (B) CsCI (C) CaF2(D) NiAs (E) ZnS

9. Which of the following statements about the structures of metals and ionic solids is (are) correct? I. Atoms in a solid consisting of only one element would have six nearest neighbors, if the crystal structure is a simple cubic array. II. There are four tetrahedral holes in a cubic closest packed unit cell. III. If the metal with an atomic radius of r has a body-centered cubic structure, the edge length of the unit cell will be . IV. For a simple cubic array, the radius of an interior sphere (cubic hole) in terms of the radius (r) of a sphere in the array is . V. Cobalt fluoride crystallizes in a cubic closest packed array of fluoride ions with the cobalt ions filling one-half of the octahedral holes, and thus the charge of cobalt ions is t3 in this compound. (A)III (B)II and V (C)III and IV (D)I, III, and IV (E)I, IV, and V

28. 根據 Raoult's law，哪個陳述是錯誤? (A)The vapor pressure of a solvent over a solution decreases as its mole fraction increases. (B) The solubility of a gas increases as the temperature decreases. (C) The vapor pressure of a solvent over a solution is less than that of pure solvent. (D)The greater the pressure of a gas over a solution the greater its solubility. (E) Ionic solutes dissociate in solution causing an enhancement of all colligative properties.

29. 依據一氧化氮氣體（Nitric oxide gas, NO）與氯氣反應方程式. 依所給定的試劑的濃度，測量以下最初始之反應速率，下列哪 項是該反應之速率定律（速率方程）?   (A) rate = k[NO] (B) rate = (C) rate = k[NO][Cl2] (D)rate = k[NO]2 [Cl2] (E) rate = k[NO]2 [Cl2]2

30. 請計算出 SeF4 中心原子周圍的孤對數和其分子幾何結構為何? (A) 0 lone pairs, tetrahedral (B) 1 lone pair, distorted tetrahedron (seesaw) (C) 1 lone pair, square pyramidal (D) 1 lone pair, tetrahedral (E) 2 lone pairs, square planar

31. 下列何種 X 和 Y 取代基組合，可形成化合物之 Z 異構物( Z isomer). (A) -Br, -NHCH3 (B) -F, -CHO (C) -I, -OCH3 (D)-COOH, -CH2NH2 (E) A 和 D 選項皆對

32. 在定溫定壓下(at constant T and P)G 呈現負值,其表示 (A)the reaction is exothermic. (B) the reaction is endothermic. (C) the reaction is fast. (D)the reaction is spontaneous. (E) S must be ＞ 0.

33. 假使一個電化學電池其標示為: 下列何者為其整 體(淨)平衡反應式？ (A) (B) (C) (D) (E)

34. 養分不足的情況下，會開始清理失常的胞器或回收老舊的蛋白質，這個過程稱為自噬作 用(autophagy)，與此過程關係最密切的胞器為何？ (A) 溶酶體 (B) 高基氏體 (C) 細胞核 (D) 過氧化體 (E)內質網

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