試卷名稱:112年 - 112 國立中山大學_碩士班暨碩士在職專班招生考試_化學系:物理化學及分析化學#126324
年份:112年
科目:研究所、轉學考(插大)◆物理化學及分析化學
7Which statement about H-atom is not true?
(A) Spherical polar coordinates are the natural choice for H-atom Schrödinger equation because the potential term is spherically symmetric.
(B) H-atom Schrödinger equation can be solved by separation of variables where the radial part Rni(r) and the angular part
are linked through I(I+1) while Θ(θ) andΦ (Φ) are linked through m².
(C) The operator for the z-component of angular momentum has the simplest form in spherical polar coordinates as opposed to the x and y-components.
(D) The rules for allowed angular momentum magnitudes and orientations are shared by the rigid rotor and the H-atom.
(E) By changing the variable sinθ into x, the Θ differential equation can be recognized as being the associated Legendre equation.