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110年 - 110 國立臺灣大學_碩士班招生考試_部分系所:(共同科目)分析化學(A)#100459
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6. Testing drivers' alcohol is an obligation should any traffic accident take place. What is the method to measure alcohol in driver's breath? If the driver refuses to take breath test, how can we measure alcohol in his blood? (20%)
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1. The dissolution of carbon dioxide in water: If the total carbon dioxide concentration is 2.2 mf, what are the concentrations (in mM units) of [HCO3], at pH 4.0, 6.4, 8.4, 10.3 and 12.5? Please give a quick estimation and explain why. (20%)
#420382
2. If the above carbonate system exists in a high saline medium (for example, seawater), the apparent dissolution constants will shift to pk1'=6.0 and pK2 =9.2. Try to use concepts related to ionic strength and activity to explain the so-calied "pKa-shifting" phenomenon. (20%)
#420383
(a) partition coefficient k'
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(b) retention time ta
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(c) flow speed u and migration speed um
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(d) height equivalent of theoretical plate (HETP)
#420387
4. What is ICP-MASS? Brief describe its principle (you may draw diagrams to make it clear). Give some examples to show its application to environmental or clinic chemistry. (20%)
#420388
5. Mercury is toxic element. The determination of mercury is largely depending upon a technique called "cold-vapor atomic absorption spectrometry". Use illustrations to describe this technique. (20%)
#420389
4. A 0.611-g sample of an alloy containing Al and Mg is dissolved and treated to prevent interferences by the alloy's other constituents. Aluminum and magnesium are precipitated using 8-hydroxyquinoline, providing a mixed precipitate of Al(C9H6NO)3 and Mg(C9H6NO)2 that weighs 7.815 g. Igniting the precipitate converts it to a mixture of Al2O3 and MgO that weighs 1.002 g. Please calculate the %w/w Al and %w/w Mg in the alloy. (Al(C9H6NO)3: MW=459.45 g/mol; Mg(C9H6NO)2: MW=312.61 g/mol; Al: MW= 26.982 g/mol; Mg: MW= 24.305 g/mol; Al2O3: MW=101.96 g/mol; MgO: MW: 40.3044 g/mol)
#527385
3. The overall Kf for the complex ion is 1.7 × 107. Ksp for AgI is 1.5 × . What is the molar solubility of AgI in a solution that is 2.0 M in NH3?
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