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97年 - 97 淡江大學 轉學考 物理化學#55524

科目：研究所、轉學考(插大)◆物理化學 | 年份：97年 | 選擇題數：0 | 申論題數：5

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所屬科目：研究所、轉學考(插大)◆物理化學

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申論題 (5)

25% 1. Two moles of an ideal gas (Cv= 1.5 R) are heated from 300K to 500K and the pressure increases fiom 2.5 atm to 4.0 atm. Calculate the entiopy change for the process.
25% 2. Consider the reaction that has the mechanism 
Derive a rate equation for the production of D in terms of concentrations of A and B.
25% 3. Consider llie reaction 
 
If K,, at 300K is 0.00216, calculate Kp at 500K, assuming that △H0 is constant. 
Data ： 
(16%) (i) Determine the eigenenergies for llie particle.
(9%) (ii) What is the degeneracy of tlie energy level E= 6 h2 / 8ma2 ( h is Planck,s constant) if the particle is in a cube?