試卷名稱:110年 - 110 國立臺灣大學_碩士班招生考試_藥學、口腔生物科學研究所:物理化學(B)#101963
年份:110年
科目:研究所、轉學考(插大)◆物理化學
1. For the reaction 2N2O5(g) 4NO2(g) + O2(g). (AB) The amount of NO2 in the reaction container is four times the amount of O2regardless how the reaction mixture is prepared for the reaction to oceur. (AC)At the moment when N2O5(g) is first transferred to the empty reaction container. the rate of disappearance of N2O5 is more than two times the rate of formation of O2. (AD) At any instant. the rate of formation of NO2 is two times the rate of disappearance of N2O5. (AE) The reaction is a second-order reaction. just like any reactions of 2M2N5 → 4MN2 + N2. (BC)If the measured initial rates are
M/sec for the initial concentrations of N2O5 of 0.0050 M and 0.010 M. respectively, the overall reaction order is one. (BD) The activation energy of the reaction may be derived from measuring the rate constants at two different temperatures.