11. Predict the major product for the following reaction.

(A)
(B)
(C)
(D)
(E)

12. Chloroquine is used as an antimalarial drug. Rank the three nitrogen atoms in decreasing (strongest to weakest) order of basicity. (A) III ＞ I ＞ II (B) I ＞ III ＞ II (C) II ＞ I ＞ III (D) II ＞ III ＞ I (E) III ＞ II ＞ I

13. Predict the product for the following reaction. (A) (B) (C) (D) (E)

14. Which of the following reaction shown below give the WRONG product? (A) (B) (C)(D) (E)

15. Choose the     correct      statement below: (A) μ3-CO has higher IR stretching frequency (ν) than terminal CO does. (B) The Ru-C distance of Ru(CE)x complexes (E=O,S,Se,Te) is the shortest when E=oxygen. (C)Linear ν(N-O) in neutral molecules is usually lower than bent ν(N-O). (D) Ni(CO)3(PCl3) has higher CO stretching frequency than Ni(CO)3(PPh3) (E) π-back bonding from CO will increase the ν(CO) in metal carbonyl complexes

16. Which of the following specifies the      incorrect      magnetic moments for the complex? (A) 4.9 BM for [Cr(H2O)6]2+ (B) 2.8 BM for [Cr(CN)6]4- (C)5.9 BM for [Fe(CN)6]3- (D) 2.8 BM for [Ni(H2O)6]2+ (E) 1.7 BM for [Cu(en)2(H2O)2]2+

17. Three separate solutions of [M(H2O)6]2+ complexes (M= Fe, Ni, and Cu) were mislabeled. In order to identify them, UV-Vis spectra were taken. Solution A has three ligand field bands. Solution B and C have only one band. Upon addition of excess CN-, the single band of Solution B shifts to higher energy while that of Solution C becomes multiband. Which of the following is correct? (A) M=Fe for Solution C (B) M=Ni for Solution B (C)M=Cu for Solution A (D) M=Cu for Solution C (E) M=Ni for Solution A

18. Choose the      correct      statement below: (A) Pure silicon is an insulator at room temperature (B) Metal has fully filled conduction band (C)Adding phosphorus in silicon makes an n-type semiconductor (D) Germanium is a p-type dopant for silicon semiconductor (E) Adding n-type dopant lowers the Fermi level

19. Which of the following name is      incorrect     ? (A) dicyanotetraкis(methylisocyano)iron(II) for [Fe(CN)2(CH3CN)4] (B) pentaamminenitridocobalt(III) sulfate for [Co(N3)(NH3)5]SO4 (C)tris(2,2'-bipyridyl)nickel(II) bromide for [Ni(bipy)3]Br2 (D) sodium tris(oxalato)vanadate(III) for Na3[V(C2O4)3] (E) potassium tetrachloroferrate(III) for K[FeCl4]

20. The enthalpy change for a reaction can be obtained by: (A) slope from plot of lnKeq vs. T (B) slope from plot of ln(1/Keq) vs. T (C)slope from plot of ln(1/Keq) vs. 1/T (D) slope from plot of lnKeq vs. 1/T (E) -RT(lnKeq)

21. What is the bond order and magnetism for Rh2(μ-CH3COO)4Cl2: (A) 3 bonds, paramagnetism (B) 2.5 bonds, paramagnetism (C)3 bonds, diamagnetism (D) 1.5 bonds, paramagnetism (E) 2 bonds, paramagnetism

115年 - [無官方正解]115 國立中山大學_碩士班考試入學招生考試試題_化學系：有機化學及無機化學#138420

114年 - [無官方正解]114 國立中山大學_碩士班考試入學招生考試試題_化學系：有機化學及無機化學#138439

113年 - 113 國立中山大學_碩士班暨碩士在職專班招生考試試題_化學系碩士班：有機化學及無機化學#119266

112年 - 112 國立中山大學碩士暨碩士專班招生考試_化學系碩士班:有機化學及無機化學#119263

111年 - 111 國立中山大學_碩士班暨碩士在職專班招生考試_化學系：有機化學及無機化學#126310

110年 - 110 國立中山大學碩士暨碩士專班招生考試_化學系碩士班:有機化學及無機化學#110464

109年 - [無官方正解]109 國立中山大學_碩士班考試入學招生考試試題_化學系：有機化學及無機化學#138499

108年 - [無官方正解]108 國立中山大學_碩士班考試入學招生考試試題_化學系：有機化學及無機化學#138538

107年 - [無官方正解]107 國立中山大學_碩士班考試入學招生考試試題_化學系：有機化學及無機化學#138542

105年 - [無官方正解]105 國立中山大學_碩士班暨碩士專班招生考試_化學系：有機化學與無機化學#138560