16. Which reaction below give the INCORRECT product for the reaction: Compound with NMe3 I- and AgO in H2O with heat gives alkene product
(A)
(B)
(C)
(D)

(E)

17. Sodium chloride is a typical example of X structure. It has Y occupying octahedral holes and Z occupying tetrahedral holes.(A) X=face-centered cubic, Y=Na+ and Cl-, Z=none(B) X=body-centered cubic, Y=Na+, Z=Cl-(C) X=face-centered cubic, Y=Na+, Z=Cl-(D) X=body-centered cubic, Y=Cl-, Z=Na+(E) None of the above

18. What is the symmetry of P2 orbital in D3d? (A) Eu(B) A1g(C) A1u(D) A2u(E) A2g

19. The intense purple colors of KMnO4 is due to:(A) Ligand to metal charge transfer(B) Metal to ligand charge transfer(C) d-d transition(D) dipole-dipole interaction(E) None of the above

20. What is the most likely transition metal M in K3[M(CN)6] having LFSE=-1.2 Δ0?(A) Ni(B) Fe(C) V(D) Cr(E) Co

21. What is the predicted magnetic moment for [FeCl4]-?(A) 4.9 μB(B) 1.7 μB(C) 2.8 μB(D) 5.9 μB(E) 0 μB

22. Which complex below is expected to show Jahn-Teller distortion?(A) [Co(CO)6]3+(B) [Cr(CN)6]3-(C) [Mn(H2O)6]2+(D) [Fe(CO)6]2+(E) None of the above

23. In a cubic unit cell, what is the intersect angle between (100) and (110)?(A) 180°(B) 45°(C) 60°(D) 30°(E) 90°

24. In CaF2 crystal, Ca2+ ions have coordination number of X while F- ions have coordination number of Y.(A) X=6 and Y=4(B) X=8 and Y=4(C) X=4 and Y=4(D) X=8 and Y=8(E) X=6 and Y=6

25. Among the listed characteristics below, which one does not belong to ionic bonding?(A) Columbic forces(B) Brittle(C) Small difference in electronegativity between bonding pairs(D) Low conductivity in solid state(E) Large bond energy

26. Which of the following statement is correct?(A) Back bonding concerns the electron donation coming from ligands to metal and yielding sigma bond(B) HOMO has higher energy levels than LUMO in molecular orbital theory(C) Compared to Lewis structure, molecular orbital theory describes bonding electrons to be more delocalized(D) The larger radius ratios of cation to anion (Rcation/Ranion), the smaller coordination numbers observed in the crystal packing(E) None of the above

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