19. The experimental rate law for the decomposition of nitrous oxide (N2O) to N2 and O2 is Rate = k[N2O]2. Two mechanisms are proposed:

I: N2O → N2 + O

N2O + O → N2 + O2

II: 2N2O → N4O2

N4O2→ 2N2 + O2 

Which of the following could be a correct mechanism?
(A) mechanism I with the first step as the rate-determining step
(B) mechanism I with the second step as the rate-determining step
(C) mechanism II with the second step as the rate-determining step
(D) two of these could be correct
(E) none of these could be correct.

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統計: A(0), B(0), C(1), D(0), E(0) #3371104

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