試題詳解

22. Methane monooxygenase (s-MMO) contains a dinuclear iron active center and is a catalyst for the oxidation of CH₄ by O₂ to form CH₃OH; the reaction process is shown below. Which of the following statements is incorrect? 

(A) Theelectronic configuration of the ground state Fe atom is [Ar]3d64s². involves the breaking of a non-polar bond and the formation of
(B) Step polar bonds.
(C) Electron transfer occurs between iron and oxygen atoms in each step.
(D) Radical species are produced during the reaction.
(E) The overall reaction shown is CH₄ + O₂ + 2H⁺ +2 CH₃OH+ H₂O