II. Physical chemistry concepts and calculations
 10. Discuss in detail (a) (i) collision theory and (il) transition state theory taught in chemical kinetics: (b) (i) Hess's law and (ii) Bomn-Haber cycle taught in thermodynamics. (20%)

11. Assume 2,000 mol O2(g) at 298.0 K and 1.00 atm behaves ideally. Calculate (i) the change in internal energy and (ii) the final temperature of the oxygen gas when 200.0 J of energy is transferred as heat to the gas at (a) constant volume: (b) constant pressure. (11%)

12. (a) A sample of ideal gas at 244 K and 2.00 atm expands from 10.0 L to 20.0 L by two different paths. Path A has two parts. In the first step. the gas is cooled at constant volume to 1.00 atm. In the second step. the gas is heated and allowed to expand against a constant external pressure of 1.00 alm until its volume is 20.0 L and T = 244 K. Path B is an isothermal. reversible expansion to reach a final pressure of 1.00 atm. Calculate for each path (i) the work done. (ii) the heat transfered. and (iii) the change in internal energy. (b) Discuss the difference in the calculated results obtained in (a) between Paths A and B and explain how the concept of state function is revcaled. (c) Can the results obtain in (a) be used to support the first law of thermodynamics? Explain. (13%)

13. A nonspontaneou us reaction can be driven to occur in biological systems by using a reaction that produces a lot of entropy in the surrounding for building and maintaining their intricate functions. Use any biological reactions as examples to discuss the physical chemistry principle behind the drive and address the related Gibbs fice encrgy changes in biological systems. (For examplc. the hydrolysis of adenosine triphosphate (ATP) to adenosine diphosphate (ADP) is the reaction used most frequently by organisms to couple and drive nonspontancous reactions. Eating food that contains glucose can heip to restore ADP back to ATP by combustion of glucose in our bodies. However. you can use whichever the reaction you know the best to answer this question.) 让脂嘘半的同 (12%)

一、(1)申論說明營建工程全生命週期管理之架構:(10分)

(2)自舉某類工程為例,按上述工程各階段展之流程,條列並概述其專案工程管理之內容要項.(15分)

二、(1)某工程建設已完成工作量的预算成本(Budgeted Cost of WorkPerformed,BCWP)為 60， 計劃工作量的預算費用(Budgeted Cost of Work Scheduled,BCWS)為20 則時程差異 (Schedule Variance,SV)為?(5分)

(2)某工程建設已完成工作量的预算成本(Budgeted Cost of WorkPefoed,BCWP為 100·已完成工作量的實際費用(Actual Costfor Work Performed ACWP)為30·本差 異(Cost Variance,CV)為?(5分)

(3)請計算於第 120天,四個計劃工作項目的預算費用Budgeted Cost of Work Scheduled,BCWS)為何?(15分)

(1)在大規模或複雜性之工程件下,工程主辦單位會將該工程劃分成若干標案進行發 包。請說明常用之工程分工分標方式?(13分)

(2)請說明常見的工程爭議處置方式?(12分)

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