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113年 - 113 國立中山大學_碩士班暨碩士在職專班招生考試試題_化學系碩士班:有機化學及無機化學#119266
> 試題詳解
5. Which of the following reaction will NOT give the product as shown?
(A)
(B)
(C)
(D)
(E)
答案:
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統計:
A(0), B(1), C(0), D(0), E(1) #3222729
詳解 (共 1 筆)
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1. What is the correct IUPAC name for the following compound? (A) (2R,5R)-5-chloro-2-methylcycloheptan-1-one (B) (2S,5R)-5-chloro-2-methylcycloheptan-1-one (C) (2R,5R)-5-chloro-2-methylcyclohexan-1-one (D) (1R,5R)-1-chloro-5-methylcycloheptan-3-one (E) (1R,4R)-4-chloro-1-methylcycloheptan-7-one
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2.Predict and arrange the reactivity of the following compounds in ascending order when reacting with HBr. (A)2<3<5<1<4 (B)5<3<2<4<1 (C)1<2<5<3<4 (D)4<1<3<5<2 (E)2<5<3<1<4
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3. Which of the following structures, if flat, can be considered aromatic? (A) 1 only. (B) 3 and 5 only. (C) 2 and 4 only. (D) 1 and 3 only. (E) None of the above.
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4. Which of the following is a correct Diels-Alder reaction product of the following reaction? (A)(B)(C)(D)(E)
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6. Consider a system in which an ester is hydrolyzed in a base catalyzed hydrolysis using potassium hydroxide as the base. After the reaction, what will happen theoretically concerning the acidity of the reaction mixture when compared to the beginning of the reaction? (A) The mixture will become more basic compared to the beginning. (B) The mixture will become more acidic compared to the beginning. (C) The acidity of the reaction mixture will not change. (D) The concept of acidity cannot be applied to organic system. (E) The exact situations depend on the actual structure of the ester.
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7. Which of the following position is the most reactive towards electrophilic aromatic substitution? (A)A(B)B(C)C(D)D(E)E
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8. Describe the number of signals and their splitting in the 1H NMR of the following compound: (A) 7 signals: 1 singlet, 2 doublets, 1 triplet, 3 quartet (B) 6 signals: 1 singlet, 3 doublets, 1 triplet, 1 quartet (C) 7 signals: 4 doublets, 2 triplet, 1 quartet (D) 7 signals: 1 singlet, 4 doublets, 1 triplet, 1 quartet (E) 8 signals: 2 singlet, 4 doublets, 1 triplet, 1 quartet
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11. Which of the following compound is the most reactive in an SN1 reaction? (A)(B)(C)(D)(E)
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