9.Graphs shown below are data obtained by the following analytical methods (from left to right): IR, NMR, EPR, and MS. What are the correct x-axis labels and units? (4%)
(A) Micrometer (um) - magnetic field (MHz) - magnetic field (G) - atomic mass unit (Da)
(B) Wavenumber (1/cm) - magnetic field (MHz) - magnetic field (G) - atomic mass unit to charge ratio (Da/z)
(C)Wavenumber (1/cm)- chemical shift (ppm) - magnetic field (G) - atomic mass unit to charge ratio (Da/z)
(D)Micrometer (μm) - chemical shift (ppm)- Coulomb （C） - atomic mass unit (Da)
(E)Wavenumber (1/cm) -chemical shift (ppm)- resistance (Ω) - atomic mass unit (Da)

5.Which of the following statements about a Fourier transform IR spectrometer is correct? (4%) (A) It accurately measures the spectroscopic response one wavelength at a time. (B)It needs more time to acquire a spectrum than a scanning IR spectrometer. (C)It is usually equipped with a monochromator. (D)The absorbance at all wavelengths are measured simultaneously. (E)This type of instrument was named after the American physicist Daniel J. Fourier.

6.Which of the following description about atomic X-ray spectrometry is NOT correct? (4%) (A)X-rays are electromagnetic radiation with very short wavelengths (≤ 10 nm). (B) X-ray line spectra involves electronic transitions of the innermost atomic orbitals. (C) The K series refers to X-radiation as a result of electrons moving from outer orbitals of an atom into a vacant orbital of the K shell. (D)The Ka line is the result of a vacant K orbital filled by an electron falling from the M shell. (E)The wavelength (energy) of the Ka lines for molybdenum is independent of its oxid ation state.

7. Which of the following description about various forms of light emission is NOT correct? (4%) (A) Fluorescence and phosphorescence signals are typically measured at a 90° angle to the excitation beam. (B) In fluorescence spectra, the emitted radiation usually has a longer wavelength than the excitation radiation; this difference is called the Stokes shift. (C)The average lifetime of an excited triplet state is orders of magnitude shorter than that of an excited singlet state. (D)Chemiluminescence occurs when a chemical reaction generates an electronically excited species; this excited molecular species then emits light as it relaxes to the ground state. (E)Chemiluminescence is usually measured without selecting a specific wavelength for detection.

8. All of the following are spontaneous reactions that proceed to the right. Standard reduction potentials at 259C are provided for some half-cell reactions. Based on this information, rank the relative strengths of H+, Ag+ , Cd2+, Cu2+, and Zn2+ as electron acceptors (oxidizing agents) at 25℃. (4%) (A) Cu2+ ＞ H+＞Ag+ ＞ Cd2+＞Zn2+ (B) Ag+＞ Cu2+＞H+> Cd2+＞Zn2+ (C) Zn2+＞ Cd+＞Ag+＞ Cu2+＞H+ (D)Zn2+＞ Cd+＞ H+＞Ag+ ＞ Cu2+(E) There is not enough information to deduce their relative oxidative strengths.

複選題 10. Which of the following description is correct? (4%) (A) The solubility product constant (Ksp) of aluminum hydroxide (Al(OH)3) is 3 ×10-34; the Ksp of cadmium sulfide (CdS) is 1× 10-27. Based on this information, we know that Al(OH)3 is less soluble than CdS in pure water. (B) A glass of aqueous solution (100 mL) contains [Ca2+] = 2.13✖10-4 M, [F-] = 4.26✖ 10 -4 M, and 0. 781 g of insoluble Caf2 solid. Based on this information, we can estimate the Ksp of Caf2 to be ~3.9 x 10-11 (C) Even through the same chemical can sometimes exist in more than one crystalline form, e.g., CaCO3 can be both calcite and aragonite, they are always equally soluble. (D) The pKa1and pKa2 of methionine are 2.28 and 9.21. Based on this information, we know that methionine has the best buffering power (capacity) at pH 5.75 (the mid-point between the two pKa values). (E) The hydrogen cation concentration ([H+]) of a pH 6.5 solution is 5.0 ✖10-7 M. 

1. 金融機構如發現客戶屬於國內較高風險的重要政治性職務人士(PEP)，應執 行強化客戶審查措施，下列敘述何者錯誤？(A)取得高階主管的核准(B)採 取合理措施，以了解客戶之財富來源及交易資金來源(C)對業務關係進行持 續的強化監控(D)立即向主管機關金管會通報有 PEP

2. 下列哪一種運輸的貨物類型容易被利用於洗錢或資恐？(A)鐵礦(B)砂石 (C)鑽石(D)成衣

3. 有關紀錄保存之規定，下列何者錯誤？(A)疑似洗錢或資恐交易之申報，其 申報之相關紀錄憑證，自申報後以原本方式至少保存五年(B)確認客戶身分 所取得之所有紀錄、帳戶檔案、業務往來資訊等，自確認後以原本方式至 少保存五年(C)達一定金額以上大額通貨交易，其確認紀錄及申報之相關紀 錄憑證，自交易後以原本方式至少保存五年(D)交易帳號、姓名、交易日 期、貨幣種類及金額等國內外交易之所有必要紀錄，自交易後應至少保存 五年

4. 有關防制洗錢及打擊資恐中確認客戶身分措施之敘述，下列何者錯誤？ (A)對於高風險情形，應加強確認客戶身分或持續審查措施(B)對於來自洗 錢或資恐高風險國家之客戶，應採行與其風險相當之強化措施(C)對於較低 風險客戶，仍不得採取簡化確認客戶身分措施(D)對於高風險客戶，在建立 或新增業務往來關係前，應取得銀行高階管理人員同意

5. 以下何者較不可能是高洗錢資恐之職業或行業？(A)證券投資顧問(B)從事 密集性現金交易業務(C)會計師、律師、公證人(D)易被運用為持有個人資 產之公司或信託